187k views
16 votes
Why can single bonds rotate freely?

User Wislo
by
5.5k points

1 Answer

13 votes
Carbon atoms in single bonds rotate freely. Rotation can occur because the heaviest electron density in the σ bond exists along an imaginary line between two carbon nuclei. Rotation does not change this electron distribution; the bond strength remains constant throughout rotation.
User Andrew Schulman
by
5.7k points