There are 36 possible outcomes from rolling a die twice (or two dice once) and these result in sums from 2 to 12.
Possible ways to make a sum of 2: 1
Possible ways to make a sum of 3: 2
Possible ways to make a sum of 4: 3
Possible ways to make a sum of 5: 4
Possible ways to make a sum of 6: 5
Possible ways to make a sum of 7: 6
Possible ways to make a sum of 8: 5
Possible ways to make a sum of 9: 4
Possible ways to make a sum of 10: 3
Possible ways to make a sum of 11: 2
Possible ways to make a sum of 12: 1
This means there are 21 ways to make a sum greater than 6.
21/36 ≈ 58.33%
There are 24 ways to make sums that are not divisible by 3 and not divisible by 6. (Note that if a number isn't divisible by 3, it's also not divisible by 6, so that's a weird thing to include.)
24/36 ≈ 66.67%