Remember that the sum of the interior angles of a triangle is always 180°. We can take advantage of that fact to find the remaining angle in triangle PQR and triangle RST:
For triangle PQR:
c = 180 - (100 + 66)
o = 180 - 166
o = 14
For triangle RST:
B = 180 - (14 + 100)
8 = 180 - 114
B = 66
Since both triangles have interior angles 100°, 66°, and 14°, we can conclude that the triangles are similar.