Answer: 0.112 atm.
Explanation:
(PV = nRT), which states that the pressure times volume of a gas is equal to the number of moles of gas times the ideal gas constant times the temperature.
Since the volume of the bottle is constant, we can rearrange the Ideal Gas Law to solve for pressure:
P = (nRT) / V
where
n = 0.000540 moles (the amount of O2 remaining after the candle goes out)
R = 8.31 J/mol*K (the ideal gas constant)
T = 35 + 273 = 308 K (the temperature in kelvins)
V = 250 mL = 0.25 L (the volume of the bottle in liters)
Plugging in the values, we get:
P = (0.000540 * 8.31 * 308) / 0.25
P = 0.112 atm
So, the pressure inside the bottle after the candle goes out is approximately 0.112 atm.