Final answer:
The concentration of the reactant after 22.0 seconds is calculated using first-order reaction kinetics, and it amounts to 0.04575 M when the initial concentration is 0.150 M and the rate constant is 5.4 x 10^-2 s^-1.
Step-by-step explanation:
To calculate the concentration of a reactant after a certain period, assuming a first-order reaction, we can use the first-order rate equation:
![[A] = [A]0e-kt](https://img.qammunity.org/2024/formulas/chemistry/high-school/iqr4zpseeog1hllm85unuu8s9xf4rsfuit.png)
Where:
- [A] is the concentration of the reactant at time t
- [A]0 is the initial concentration of the reactant
- k is the rate constant
- t is the time
Using the given values, the initial concentration [A]0 is 0.150 M, the rate constant k is 5.4 x 10-2 s-1, and time t is 22.0 s.
[A] = 0.150e-(5.4 x 10-2)(22.0)
Calculating the exponent first:
-5.4 x 10-2 x 22.0 = -1.188
Now, substituting this back into the equation:
[A] = 0.150e-1.188
Using a calculator to find the value of e-1.188, we find:
[A] = 0.150 x 0.305 = 0.04575 M
Therefore, the concentration of the reactant after 22.0 seconds is 0.04575 M.