If 3.2 moles of Cl2 are added to Na, the number of moles of NaCI produced would be 3.2 moles. According to the balanced equation, 2 moles of Na are needed to react with 1 mole of Cl2 to form 2 moles of NaCl. Since 3.2 moles of Cl2 are used in the reaction, 3.2 moles of NaCl will be produced.
In terms of the number of molecules, we can use Avogadro's number (6.022 x 10^23) to convert moles to molecules. Therefore, 3.2 moles of NaCl would be equal to (3.2 moles) x (6.022 x 10^23 molecules/mol) = 1.93 x 10^24 molecules of NaCl.