you must use the process known as dimensional analysis. start with what the problem gives you, which in this case is g of AlCl3!
(45.2 g AlCl3) * (1 mol AlCl3/133.33g AlCl3) * (6mol HCl/2mol AlCl3) * (36.46gHCl/1molHCl)
Now multiply across. the correct answer should cancel all units except g HCl, since that is what the problem asks for
34.9 g HCl is required!