Answer: The mass of aluminium metal that must be added is 27.0 grams
Step-by-step explanation:
We are given:
Volume of hydrogen gas = 33.6 L
At STP conditions:
22.4 L of volume is occupied by 1 mole of a gas
So, 33.6 L of volume will be occupied by =
of hydrogen gas
The chemical equation for the reaction of aluminium metal and HCl follows:

By Stoichiometry of the reaction:
3 moles of hydrogen gas is formed by 2 moles of aluminium metal
So, 1.5 moles of hydrogen gas will be formed by =
mole of aluminium metal
To calculate the number of moles, we use the equation:

Moles of aluminium metal = 1 mole
Molar mass of aluminium = 27.0 g/mol
Putting values in above equation, we get:

Hence, the mass of aluminium metal that must be added is 27.0 grams