First, we need to make difference between the 2 solutions here.
Solution 1)
Volume 1 = V1 = 85.0 mL = 0.0850 L (volume of solution)
Concentration 1 = C1 = 0.400 mol/L
Solution 2)
V2 = Need to be found
C2 = 0.250 mol/L
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We want to get from Solution 1 to Solution 2 by adding water, so we dilute solution 1. To this we use this formula:
C1 x V1 = C2 x V2, we clear V2, so we get to
V2 = volume of solution 2 = 0.136 L
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The volume of water we need to add solution 1 is:
V2 - V1 = V of water added = 0.136 L - 0.085 L = 0.0510 L of water
Answer: 0.0510 L of water