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The Hittites were the first society to use this as a weapon.

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The Hittites were allegedly the first society who used chariots as war machines with javelinists or bowmen which enabled them to win battles as such a war device wasn't in use at the time by other nations. However, there has been some dispute whether the Hittites were actually the first society who used chariots as a means of war. 
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