Samuel de Champlain met the leader of the Montagais tribe first.The correct option to the given question is option "D". Samuel de Champlain was known as the Father of New France and he was also a great navigator. He met the chief or the leader of the Montagnais tribe in Tadoussac. Samuel de Champlain was born on 15th of August in the year 1574 in France. He died in Canada on 25th December in the year 1635. He was not only a great navigator but also a cartographer, ethnologist, diplomat, draughtsman, soldier and a geographer. He was born in the family of mariners and so had a thirst for new discoveries around the globe.