Answer is (4) - CH₃CH₂OH and CH₃OCH₃.
Both CH₃CH₂OH and CH₃OCH₃ have same molecular formula as C₂H₆O. But CH₃CH₂OH is an alcohol and CH₃OCH₃ is an ether.
Although two compounds have a same molecular formula, the atomic arrangement of those compounds differs from each other.
Hence, CH₃CH₂OH and CH₃OCH₃ are isomers of the formula C₂H₆O.
Due to the different arrangement of atoms, both compounds have different chemical and physical properties.