Answer: The water is unsafe to drink because 30.4 ppm > 4 ppm.
Explanation: The recommended concentration of fluoride in the water is 4.00 ppm. If the concentration of fluoride increases the recommended limit, the water is unsafe to drink and vice-versa.
Parts Per Million (ppm) is the measurement of the concentration of the solution. It is expressed in mg/kg, which means:

We are given a sample of 5.00 grams and the solute is fluoride which has a weight of 0.152 mg.
Weight of the sample = 5.00 grams = 0.005 kg (Conversion factor: 1 kg = 1000g)
Putting values in ppm equation, we get:

As the ppm value is more than the recommended value. Hence, the water is unsafe to drink.