Answer: The correct answer is Argon.
Step-by-step explanation:
Ionization energy is defined as the energy required to remove valence electron from an isolated gaseous atom. It is expressed as


Energy required for a stable molecule (having fully filled and half filled electronic configuration)
The electronic configuration for the elements given are:
1. Na:

As, this element does not have stable electronic configuration. So, this will not have highest ionization energy.
2. Al:
As, this element does not have stable electronic configuration. So, this will not have highest ionization energy.
3. Si:

As, this element does not have stable electronic configuration. So, this will not have highest ionization energy.
4. Ar:

As, this element have stable electronic configuration where all the orbitals are fully filled. thus, this element will require more energy to remove the valence electron. So, this have highest ionization energy.
Hence, the correct answer is Argon.