Answer: The correct answer is Option D.
Step-by-step explanation:
For two species to react, the collision between the atoms must be effective.
The chemical equation for the reaction illustrated in the image follows:

Chlorine and hydrogen atoms are getting attached to the reactant, therefore they are participating in the reaction.
There are 2 factors on which the effective collisions depends:
- Energy factor: This factor states that the colliding molecules must have energy greater than the threshold energy.
- Orientation factor: This factor states that the colliding molecules must have a proper orientation at the time of collision.
In the image illustrated, the orientation of the reactant is not proper for the collision. Hence, the correct answer is Option D.