To solve this we use the equation,
M1V1 = M2V2
where M1 is the concentration of the stock solution, V1 is the volume of the stock solution, M2 is the concentration of the new solution and V2 is its volume.
4.5 ( V1 ) = 3.0 ( 500 mL )
V1 = 333.33 mL needed of the 4.5 M phosphoric acid
Hope this answers the question. Have a nice day.