1) Determine the number of moles of chlorine gas
At STP 1 mol = 22.4 liter
=> [1mol/22.4 liter] * 0.050 liter = 0.00223 mol Cl2 (g)
2) Write the balanced equation
4HCl (g) + O2 --> 2Cl2 (g) + 2H2O (g)
3) Write the ratios of the compound on which you are focused.
4 HCl : 2 mol Cl2
Then, 0.00223 mol Cl2 * [4mol HCl / 2 mol Cl2] = 0.00446 mol HCl
5) Use Avogadro's number to find the number of molecules:
0.00446 mol * 6.02*10^23 = 2.68 * 10^21 molecules of HCl
Answer: 2.68 * 10^21 molecules