empirical formula is the simplest ratio of whole numbers of components making up a compound
the percentages have been given so we are finding masses for 100 g of the compound
Na S O
mass 36.48 g 25.41 g 38.11 g
number of moles
36.48 g/23 g/mol 25.41 g /32 g/mol 38.11 g / 16 g/mol
= 1.6 = 0.8 = 2.4
divide by the least number of moles
1.6 / 0.8 = 2 0.8/0.8 = 1 2.4 / 0.8 = 3
the number of atoms of each element
Na - 2
S - 1
O - 3
empirical formula is - Na₂SO₃