Final answer:
The statements about electron configurations and the periodic table are evaluated as mostly false, with only two being true. The true statements confirm that the highest quantum number for period 2 elements is 2 and that group 8A elements have filled outer shells.
Step-by-step explanation:
To classify each statement as true or false regarding electron configurations and the periodic table:
True: The highest principal quantum number of period 2 element is 2.
False: Period 4 elements have an inner electron configuration of [Ar]. They instead have an inner electron configuration ending in [Kr].
False: The valence electrons of groups 5A elements are not in the 6s subshell; they are in the 5p subshell.
True: Group 8A elements have completely full outer principal shells.
False: Period 5 elements do not have an inner electron configuration of [Xe], but actually [Kr].
True: The valence electrons of group 2A elements are indeed in an s subshell, specifically the 'ns' subshell where 'n' is the period number.
False: The highest principal quantum number of period 3 element is 3.
False: Period 3 elements do not all have six 2p electrons. For example, Sodium (Na) has only one 3s electron beyond the 2p sublevel, hence not all elements in period 3 have filled 2p orbitals.