this is a stoichiometry based problem
We can solve this by just knowing the balanced chemical equation.The reaction where PbO2 is used and water is produced is
Pb + PbO2 + 2H2SO4 ----> 2PbSO4 + 2H2O
This is reaction in lead storage battery
so here as per balanced equation one mole of PbO2 is consumed giving two moles of water
so if 5.43 moles of PbO2 we will get = 2 X 5.43 moles of water = 10.86 moles