Empire's are huge and sometimes even span numerous continents as they are usually made by conquering others. A modern example can be the British Empire that spanned from the US in the west, up till China in the east. Civilizations and states are usually based around a single culture or a single religion predominantly, while Empires have even countries where the people are completely different. Empires are ruled by Kings and Tsars, Emperors, while states are usually governed by smaller kings or presidents or similar.