Although you didn't include the table, I can see that you can build a system of three equations with three variables.
Let the variables K, E and S be the number of hours Katie, Elizabeth and Siobhan volunteer, respectively, in a week.
Then
Katie volunteers 3 hours more than Elizabeth
1) K = 3 + E
Siobhan volunteers 1 hour less than Elizabeth
2) S = E -1
Over three weeks, the number of hours Katie volunteers is equal to the sum of Elizabeth's and Siobhan's.
3) 3K = 3 (E + S).
Now you can solve the system in many ways. I will show which I think is easiest.
First, simplify #3) dividing both sides by 3 to get
4) K = E + S (this is the same # 3 simplified)
Use # 1 and # 4 to obtain
3 + E = E + S
Subtract E from both sides to get
S = 3.
Now you can subtract # 2 from # 1 to get
K - S = 3 + E - (E -1)
K - S = 3 + 1
K - S = 4
K = S + 4
K = 3 + 4 = 7
Now I will use # 2 to obtain E
S = E - 1
E = S + 1
E = 3 + 1
E = 4.
Now you have all the number of hours:
K = 7
E = 4
S = 3
You can (and should) check that those results match the statements.