Answer is: 89.6 liters.
Balanced chemical reaction:
CS₂ + 3O₂ → CO₂ + 2SO₂.
n(CS₂) = 2.00 mol; amount of carbon disulfide.
From balanced chemical reaction: n(CS₂) : n(SO₂) = 1 : 2.
n(SO₂) = 2 · 2 mol.
n(SO₂) = 4.00 mol; amount of sulfur dioxide.
V(SO₂) = n(SO₂) · Vm.
V(SO₂) = 4 mol · 22.4 L/mol.
V(SO₂) = 89.6 L; volume of sulfur dioxide.