Answer: The correct option is C.
Step-by-step explanation:
ppm : It is used to measure the concentration of solute in a given volume of solution. ppm is basically parts per million.
Formula used :

We are given :
Mass of methanol =

(Conversion Factor : 1g = 1000mg)
Volume of solution = 250 mL = 0.250L (Conversion Factor : 1L = 1000mL)
Now put all the given values in above equation, we get:

Concentration of methanol = 0.061ppm
Hence, the correct option is C.