1) Calculate the number of mols,n, of the substance
n = mass/ molar mass = 326.0 g / 58.45 g / mol = 5.577 moles
2) Calculate the molar heat of fusion as the total heat released by the sample divided by the number of moles
hf = heat released / n = 4325.8 cal / 5.577 moles = 775. 59 cal /mol