If you wanna estimate the probability of an event to happen, you have to multiply the probability of success of all the situations involved.
- Probability to get the first sweatshirt made of cotton: 7 of 16.
- Probability for the second one: 6 of 15, because there's one shirt less, and one cotton less.
- Prob for the third: 5 of 14
- Prob for the fourth: 4 of 13
So the probability to get four cotton shirts is: 7/16·6/15·5/14·4/13 = 0'019, something that could be rounded to 2%.