Answer : The correct option is, (2)

Explanation :
Arrhenius theory : It sates that an acid is a type of substance that ionizes in the water to give the hydronium ion or hydrogen ion
and a bases is a type of substance that ionizes in the water to give hydroxide ion
.
Or we can say that,
Arrhenius acid are those which can easily gives the hydrogen ion in a solution and Arrhenius base are those which can easily gives the hydroxide ion in a solution.
In option 1,
can easily gives the hydrogen ion but
can not gives the hydrogen ion due to stronger O-H bonding. So, these formulas does not represent Arrhenius acids.
In option 2,
and
can easily gives the hydrogen ion. So, these formulas represent Arrhenius acids.
In option 3,
and
can not gives the hydrogen ion because both are the salts. So, these formulas does not represent Arrhenius acids.
In option 4,
and
can not gives the hydrogen ion because no hydrogen present in the compound. So, these formulas does not represent Arrhenius acids.
Hence, (2)
represent Arrhenius acids.