Answer:
Sample A is a mixture
Sample B is a mixture
Step-by-step explanation:
If we look at sample A, we can easily notice that the sample powder was found to float while some of it settled below. This means that the sample is not entirely homogeneous. A homogeneous sample always constitutes a single phase in solution. Also, the dried mass yields 50.1 g while only 50.0 g of the yellow cube was ground and dissolved. This shows that the original cube is not pure. A sample that is not entirely homogeneous is not pure.
Secondly, the fact that the density of liquid that remains in the flask is different from the density of the sample initially measured indicates that the original sample B is a mixture of substances.