Step-by-step explanation:

According to reaction, 2 atoms of aluminum gas reacts with 3 molecules of chlorine gas.
Then 20 atoms of aluminum will react with :
of chlorine
Aluminum is a limiting reagent.
Molecules of chlorine left unreacted: 45 - 30 molecules = 15 molecules
Then 15 molecules of chlorine gas will react with :
of aluminum
10 more atoms of aluminum will required to use up all chlorine.