To answer this we need to assume that at STP 1 mol of a substance is equal to 22.4 L. We use this data for the calculations.
Statement 1
2 mol HCl (1 mol H2 / 2 mol HCl) = 1 mol H2 thus at STP 22.4 L H2
This statement is false.
Statement 2
1 L Zn (1 mol Zn / 22.4 L Zn) (1 mol H2 / 1 mol Zn) (22.4 L H2 / 1 mol H2) = 1L H2
This statement is true.
Statement 3
65.39 g Zn (1 mol Zn / 65.39 g Zn) (1 mol H2 / 1 mol Zn) = 1 mol H2
This statement is true.
Statement 4
1L HCl (1 mol HCl / 22.4 L HCl)(1 mol H2 / 2 mol HCl) = 0.022 mol H2
This statement is false.