Answer:
c) C₃H₆ and CH₄
Step-by-step explanation:
The empirical formula is obtained from a molecular formula by dividing it with a whole number with which all elements are divisible completely. Empirical formula is the simplest ratio of all the elements present in a molecule.
Let us consider all the examples
a) C₂H₆ and C₆H₁₈
Empirical formula of C₂H₆ = CH₃[by dividing with two]
Empirical formula of C₆H₁₈= CH₃ [by dividing with six]
b) C₃H₆O₃and C₂H₄O₂
Empirical formula of C₃H₆O₃ = CH₂O[by dividing with three]
Empirical formula of C₂H₄O₂= CH₂O [by dividing with two]
c) C₃H₆ and CH₄
Empirical formula of C₃H₆ = CH₂[by dividing with three]
Empirical formula of CH₄= CH₄ [already simplest ratio]
So these are not same.
d) CH₂O and C₃H₆O₃
Empirical formula of C₃H₆O₃ = CH₂O[by dividing with three]
Empirical formula of CH₂O= CH₂O [already simplest ratio]