Final answer:
The hydronium ion concentration in the given solution is 4.44 x 10-13 M, and the pH is 12.35.
Step-by-step explanation:
To find the hydronium ion concentration and pH of an aqueous solution of NH3 with a hydroxide ion concentration of 2.25 x 10-2 M:
Step 1: Write down the chemical equation for the ionization of NH3 in water, which is: NH3 + H2O ⇌ NH4+ + OH-
Step 2: Since NH3 is a weak base, and the hydroxide ion concentration is given, we can assume that the concentration of NH3 is equal to the concentration of OH-. So, the concentration of NH3 is 2.25 x 10-2 M.
Step 3: Use the equation for water autodissociation: Kw = [H3O+][OH-]
Step 4: Substitute the known values into the equation: [H3O+][2.25 x 10-2] = 1.0 x 10-14
Step 5: Solve for [H3O+]: [H3O+] = 1.0 x 10-14 / (2.25 x 10-2) = 4.44 x 10-13 M
Step 6: Calculate the pH using the equation: pH = -log[H3O+]
Step 7: Substitute the value of [H3O+] into the equation: pH = -log(4.44 x 10-13) = 12.35
Therefore, the hydronium ion concentration is 4.44 x 10-13 M and the pH is 12.35.