In this question , we will have to calculate the wavelength for each of the given answer choices, the shortest wavelength is the answer .
1. n = 3 to n = 1
we will use rydberg formula for wavelength : let represent wavelength.
1/ = RH * z^2 ( 1/n1^2 - 1/n2^2) ......{n1 = 1 , n2 = 3}
1/ = RH * z^2( 1/1-1/9)
1/ = 1.09x10^7*1 (8/9)
∴ =1.03x10^-7
2. n = 2 to n = 1
1/ = RH * z^2 ( 1/1^2 - 1/2^2)
=1.09x10^7*1 ( 3/4)
1/ =8175000
∴ =1.22x10^-7
3. n = 4 to n = 1
1/ = -10218750
∴ = -9.7x10^-8
4 . n = 4 to n = 3
1/ = -529861.1
∴ = -1.88x10 ^-6
5. n = 4 to n = 2
1/ = -4768750
∴ =-4.89x10^-7
• Finally, we can see that option C is the most negative value, ,∴, = -9.7x10^-8