Answer:
The pope deemed her a heretic because she declared the Church of England independent of Vatican authority.
Explanation.
Before Queen Elizabeth I, Queen Mary I who was Elizabeth's predecessor had returned the Church of England and the Church of Ireland back to Catholicism and the authority of the Vatican.
When Queen Elizabeth declared the Church of England to be free of Vatican authority, it prompted Pope Pius V to excommunicate her. and to incite rebellion against her rule and authority.