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A certain food web is made up of phytoplankton, emperor penguins, seals, and krill. Which organism is most likely the producer in this food web?

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Phytoplankton, because when taking all of those animals into consideration, the web would be like this
Seals-carnivore
Emperor Penguin (eats krill)
Krill (eats phytoplankton)
Phytoplankton <--Bottom of the web
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