Final answer:
The black colored precipitate formed when Fe(NO3)2(aq) and Na2S(aq) are mixed is Iron(II) sulfide, represented by the compound FeS.
Step-by-step explanation:
When Fe(NO3)2(aq) and Na2S(aq) are mixed, a precipitation reaction occurs. According to solubility rules, sulfides are generally insoluble, except for those of group 1 elements (like Na) and ammonium. Iron sulfide, which is not an exception to this rule, will precipitate as a solid. The black colored precipitate that forms is likely to be FeS (Iron(II) sulfide).
The relevant reaction can be represented by the ionic equation: Fe2+ (aq) + S2- (aq) → FeS (s), where the precipitate is the insoluble iron(II) sulfide.
While the information provided with the question includes several reactions and solubility examples, the key to answering this specific question is understanding the solubility of sulfides and that iron can form a black colored sulfide precipitate.