Let us say that:
x = the time it take for the new pump to drain the pool alone
4x = the time it take for the older pump
And we are given that together they drain the pool in 4 hours, therefore:
1/x + 1/4x = ¼
Multiply everything by x:
1 + ¼ = ¼ x
1.25 = 0.25 x
x = 5 hours
So, 4x = 20 hours
Hence it take the older pump 20 hours draining alone.