Final answer:
In a polar covalent bond like Si-Br, the atom that attracts the electrons more strongly acquires the partial negative charge, while the other atom has a partial positive charge.
Step-by-step explanation:
When the atoms linked by a covalent bond are different, the bonding electrons are shared, but no longer equally. Instead, the bonding electrons are more attracted to one atom than the other, giving rise to a shift of electron density toward that atom. This unequal distribution of electrons is known as a polar covalent bond, characterized by a partial positive charge on one atom and a partial negative charge on the other. The atom that attracts the electrons more strongly acquires the partial negative charge and vice versa. For example, in the H-Cl bond of a hydrogen chloride molecule, the chlorine atom carries a partial negative charge and the hydrogen atom has a partial positive charge.