In the figure, PQ is parallel to RS, then
- ∠TPQ≅∠TRS (as corresponding angles);
- ∠TQP≅∠TSR (as corresponding angles).
Consider triangles TPQ and TRS. These triangles are similar by AAA theorem, because
- ∠TPQ≅∠TRS (as corresponding angles);
- ∠TQP≅∠TSR (as corresponding angles);
- ∠T is common.
Then

If PR = 4 cm and PT = 16 cm, then TR = TP + PR = 16 + 4 = 20 cm.
Thus,

Note that TQ + QS = TS, then QS = TS - TQ = 25 - 20 = 5 cm.
Answer: correct choice is A