To solve this we assume that the gas is an ideal gas. Then, we can use the ideal gas equation which is expressed as PV = nRT. At number of moles the value of PV/T is equal to some constant. At another set of condition of temperature, the constant is still the same. Calculations are as follows:
P1V1/T1 = P2V2/T2
P1 = P2V2T1/T2V1
P1 = (114)(1.32)(596)/(715)(.654)
P1 = 191.80 kPa