We assume that the gas is an ideal gas. Then, we can use the ideal gas equation which is expressed as PV = nRT. The number of moles is constant so the value of PV/T is equal to some constant. At another set of conditions, the constant is still the same. Calculations are as follows:
P1V1/T1 = P2V2/T2
V2 = P1V1T2/T1P2
V2 = 0.4(21.7)(323) / 252 (2)
V2 = 5.56 L