(a). As the decay of pion into two phtotons takes place in the train.
The two photons are having equal and opposite momentum in the train.
As one is heading to the front of train and other is heading back.
According to the person on the train, the events seems normal.
Thus, both the photons are traveling are traveling with same speed and reach at the same time.
Hence, third option (they both arrives at the same time) is the correct answer.
(b). According to the person on the Lab frame (rest), the velocity of both the photons changes.
Thus, the time taken by the photons to reach is different.
As the photon traveling towards the right (front of car) is seems to be traveling faster and the photon which is moving towards the back of the car is seems to be traveling slower.
Hence, no is the correct answer.