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Why do polar compounds tend to have higher melting boiling points than nonpolar compounds?

User Timemanx
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2 Answers

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Because substances with hydrogen bonding will have much higher melting and boiling points than substances with ordinary dipole-dipole forces. Non-polar molecules have the lowest melting and boiling points because they are held together by the weak van der Waals forces. 
User Dwich
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Answer:

Nonpolar molecules only have Van der Waals forces between them.

Step-by-step explanation:

Ap3x

User Puneet Sharma
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