Answer:
Option D. 45° and 135° is correct.
Explanation:
For better explanation of the solution, see the attached figure below :
Now, in ΔBCD
Take BC = d = 3 unit and CD = b = 5 unit,
And, ∠D = 25°,
So, By using sine law in the ΔBCD , We have

Hence, The approximate value of ∠B = 45°
Also, The exterior value of ∠B can be used by using linear pair property
⇒ ∠B = 180 - 45
⇒ ∠B = 135°
Therefore, Option D. 45° and 135° is correct.