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A sample contains 2.2 g of the radioisotope niobium-91 and 15.4 g of its daughter isotope, zirconium-91. how many half-lives have passed since the sample originally formed?

User Trydis
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2 Answers

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3 half lives

Hope I helped :>

User Billda
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3 votes

Answer: 3

Explanation: This is a radioactive decay and all the radioactive process follows first order kinetics.

Equation for the reaction of decay of
_(19)^(40)\textrm{K} radioisotope follows:


Moles of zirconium=\frac{\text{Given mass}}{\text{Molar mass}}=(15.4)/(91)=0.17moles


Moles of niobium=\frac{\text{Given mass}}{\text{Molar mass}}=(2.2)/(91)=0.024moles


_(41)^(91)\textrm{Nb}\rightarrow _(40)^(91)\textrm{Zr}+_(+1)^0e

By the stoichiometry of above reaction,

1 mole of
_(40)^(91)\textrm{Zr} is produced by 1 mole
_(41)^(91)\textrm{Nb}

So, 0.17 moles of
_(40)^(91)\textrm{Zr} will be produced by =
(1)/(1)* 0.17=0.17\text{ moles of }_(40)^(91)\textrm{Nb}

Amount of
_(82)^(212)\textrm{K}

decomposed will be = 0.17 moles

Initial amount of
_(40)^(91)\textrm{Nb} will be = Amount decomposed + Amount left = (0.17 + 0.024)moles =0.194 moles


a=(a_o)/(2^n)

where,

a = amount of reactant left after n-half lives = 0.024


a_o = Initial amount of the reactant = 0.194

n = number of half lives= ?

Putting values in above equation, we get:


0.024=(0.194)/(2^n)


n=3

Therefore, 3 half lives have passed.

User Taekahn
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