Final answer:
The initial volume of the hydrogen gas at 50.0 °C, after lowering the temperature to -5.0 °C and having a final volume of 212 cm^3, was 0.255 dm^3, calculated using Charles's law.
Step-by-step explanation:
The question involves the relationship between temperature and volume of a gas which is described by Charles's law. This law states that at constant pressure, the volume of a given mass of an ideal gas increases or decreases by the same factor as its temperature (in Kelvin) increases or decreases.
To find the initial volume of the hydrogen gas in dm3, we first convert the temperatures from Celsius to Kelvin by adding 273.15:
- Initial temperature: 50.0 °C = 50.0 + 273.15 = 323.15 K
- Final temperature: -5.0 °C = -5.0 + 273.15 = 268.15 K
The volume at -5.0°C is 212 cm3, which we convert to dm3 by dividing by 1000 (since 1 dm3 = 1000 cm3):
212 cm3 = 0.212 dm3
Now, applying Charles's law (V1/T1 = V2/T2), we can solve for the initial volume (V1):
V1 = V2 × (T1/T2)
V1 = 0.212 dm3 × (323.15 K / 268.15 K)
V1 = 0.212 dm3 × 1.2050
V1 = 0.255 dm3
The initial volume of the hydrogen was 0.255 dm3.