Recall that:
1) Two angles are supplementary angles if their measures add up to 180 degrees.
2) Linear pair of angles are two angles that form a straight angle, therefore their measures add up to 180 degrees.
3) Adjacent angles are two angles that have a common side and a common vertex (corner point) but do not overlap in any way.
4) Vertical angles are a pair of opposite angles formed by intersecting lines. Two vertical angles are always congruent.
Therefore, the only condition that guarantees the congruence of two angles is option 4.
Answer: Option 4.