You do these problems by finding the heat of formation of each compound, from a table.
Then the heat of reaction is the (sum of the heats of formation of the products) minus (sum of the heats of formation of the reactants).
In your case, the ∆Hrxn = 5∆Hf(O2(g)) + 2∆Hf(C2H2(g)) - 2∆Hf(H2O(g)) - 4∆Hf(CO2(g)).