On a dice, there are 6 sides, there's a side with 1,2,3,4,5, and 6
so there is a 1/6 chance to roll a 6
There is a 6/6 probability that you will roll either a six, or not a six. Because there is a 5/6 chance you will not roll a six and a 1/6 chance you will roll a six
1/6+5/6=6/6
There is a 5/6 chance that you will not roll a six.
Out of the 6 numbers on the dice, 5 of them are not 6
so there is a 5/6 chance you will not roll a 6