Okay buddy, this was a lot of work. I had to pull out a piece of paper and some notes. This is what I have:
A. Subclavian Artery - 1. The Brain.
B. Vertebral Artery - 3. Spinal Column and Brain.
C. External Carotid - 4. The Face.
D. Brachiocephalic Artery - 2. Right arm, Head, and Shoulder.
E. Internal Carotid - 5. Shoulder.
I hope this is the answers you were looking for and that it helps tremendously. I was getting frustrated but pulled through. :)))))